EzCatDB

R L C P
Hierarchic Classification of Catalytic Mechanisms


R 4.-.-.- : Addition to double-bond (new bond formation and decreased bond-order) (Reaction)


Ligand groups involved

  • 4.12.-.- : Water (H2O; hydration) to Imine carbon (sp2) [leading to hydorxyl group & amine group]
  • 4.15.-.- : Water (H2O; hydration) to CO2 [leading to hydorxyl group & carboxylate; fixation of CO2]
  • 4.16.-.- : Water (H2O; hydration) to sp2-like Carbon (C=O-PO3) [leading to HO-C-OPO3]
  • 4.23.-.- : Hydroxyl oxygen to Carbon (sp2) (with carboxylate group)
  • 4.121.-.- : Carbon (sp3) (adjacent to double-bonded sp2 carbon ) to Carbonyl carbon (sp2)
  • 4.151.-.- : Carbon (sp2) (C=C-O) to Carbonyl carbon (sp2)
  • 4.162.-.- : Carbon (sp2) (C=C-N) to Imine carbon (sp2)
  • 4.191.-.- : Aromatic carbon (sp2) (C=C-N) to Carbonyl carbon (sp2) [leading to hydorxyl group & imine group]
  • 4.202.-.- : Amine group (sp3 nitrogen) to Imine carbon (sp2)
  • 4.501.-.- : Sulfur to Carbonyl carbon (sp2)
  • 4.504.-.- : Sulfur to Carbon (sp2) adjacent to double-bond
  • 4.1010.-.- : Water (H2O; hydration) to Carbon (sp2) adjacent to double-bond; Opposition to non-beta-elimination
  • 4.1034.-.- : Carboxylate oxygen to Carbon (sp2) adjacent to double-bond; Opposition to non-beta-elimination
  • 4.1164.-.- : Carbon (sp2) (C=C-N) to Carbon (sp2) adjacent to double-bond; Opposition to non-beta-elimination
  • 4.1244.-.- : Nitrogen atom in aromatic ring (sp2 nitrogen group) to Carbon (sp2) adjacent to double-bond; Opposition to non-beta-elimination
  • 4.1504.-.- : Sulfur to Carbon (sp2) adjacent to double-bond; Opposition to non-beta-elimination
  • 4.1514.-.- : Sulfur to Carbon (sp2) adjacent to double-bond; Opposition to non-beta-elimination
  • Copyright: Nozomi Nagano, JST & CBRC-AIST
    Funded by PRESTO/Japan Science and Technology Agency (JST) (December 2001 - November 2004)
    Funded by Grant-in-Aid for Publication of Scientific Research Results/Japan Society for the Promotion of Science (JSPS) (April 2005 - March 2006)
    Funded by Grant-in-Aid for Scientific Research (B)/Japan Society for the Promotion of Science (JSPS) (April 2005 - March 2008)
    Funded by BIRD/Japan Science and Technology Agency (JST) (September 2005 - September 2008)
    Funded by BIRD/Japan Science and Technology Agency (JST) (October 2007 - September 2010)
    Funded by Grant-in-Aid for Publication of Scientific Research Results/Japan Society for the Promotion of Science (JSPS) (April 2011 - March 2012)
    Funded by Grant-in-Aid for Publication of Scientific Research Results/Japan Society for the Promotion of Science (JSPS) (April 2012 - March 2013)
    Supported by the commission for the Development of Artificial Gene Synthesis Technology for Creating Innovative Biomaterial from the Ministry of Economy, Trade and Industry (METI) (October 2012 - March 2016)
    Funded by the project commissioned by the New Energy and Industrial Technology Development Organization (NEDO) (April 2016 -)