EzCatDB

R L C P
Hierarchic Classification of Catalytic Mechanisms


R 5.-.-.- : Eliminative double-bond formation (bond cleavage and increased bond-order) (Reaction)


Ligand groups involved

  • 5.10.-.- : Hydroxyl group (dehydration) from Carbon (sp3)
  • 5.12.-.- : Hydroxyl group (dehydration) from Carbon (sp3) (with amine group) [leading to imine group]
  • 5.14.-.- : Hydroxyl group (dehydration) from Carbon (sp3) adjacent to double-bond
  • 5.20.-.- : O-glycoside group from Carbon (sp3)
  • 5.21.-.- : O-glycoside group from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.30.-.- : Carboxyl ester (oxygen) from Carbon (sp3)
  • 5.41.-.- : Phosphoryl oxygen (O3P-O-) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.104.-.- : Carbon (sp3) from Carbon (sp3) adjacent to double-bond
  • 5.105.-.- : Carbon (sp3) from Carboxylate (sp2) [release of CO2]
  • 5.111.-.- : Methylene (adjacent to double-bonded sp2 carbon ) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.115.-.- : Methylene (adjacent to double-bonded sp2 carbon ) from Carboxylate (sp2) [release of CO2]
  • 5.121.-.- : Carbon (sp3) (adjacent to double-bonded sp2 carbon) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.125.-.- : Carbon (sp3) (adjacent to double-bonded sp2 carbon) from Carboxylate (sp2) [release of CO2]
  • 5.151.-.- : Carbon (sp2) (C=C-O) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.161.-.- : Carbon (sp2) (C=C-N) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.171.-.- : Carbon (sp2) (C=N-X) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.191.-.- : Cyanide group (CN) from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.200.-.- : Amine group from Carbon (sp3)
  • 5.201.-.- : Amine group from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.202.-.- : Amine group from Carbon (sp3) (with amine group) [leading to imine group]
  • 5.203.-.- : Amine group from Carbon (sp3) (with carboxylate group)
  • 5.204.-.- : Amine group from Carbon (sp3) adjacent to double-bond
  • 5.300.-.- : Phosphate group from Carbon (sp3)
  • 5.303.-.- : Phosphate group from Carbon (sp3) (with carboxylate group)
  • 5.304.-.- : Phosphate group from Carbon (sp3) adjacent to double-bond
  • 5.305.-.- : Phosphate group from Carboxylate (sp2) [release of CO2]
  • 5.501.-.- : Sulfide from Carbon (sp3) (with hydroxyl group) [leading to carbonyl group]
  • 5.524.-.- : Sulfoxide group from Carbon (sp3) adjacent to double-bond
  • 5.1020.-.- : O-glycoside group from Carbon (sp3) adjacent to double-bond: Non-beta elimination
  • 5.1202.-.- : Amine group from Carbon (sp3) adjacent to double-bond with amine group [leading to imine group]: Non-beta elimination
  • 5.1204.-.- : Amine group from Carbon (sp3) adjacent to double-bond: Non-beta elimination
  • 5.1304.-.- : Phosphate group from Carbon (sp3) adjacent to double-bond: Non-beta elimination
  • 5.1504.-.- : Sulfide from Carbon (sp3) adjacent to double-bond: Non-beta elimination
  • Copyright: Nozomi Nagano, JST & CBRC-AIST
    Funded by PRESTO/Japan Science and Technology Agency (JST) (December 2001 - November 2004)
    Funded by Grant-in-Aid for Publication of Scientific Research Results/Japan Society for the Promotion of Science (JSPS) (April 2005 - March 2006)
    Funded by Grant-in-Aid for Scientific Research (B)/Japan Society for the Promotion of Science (JSPS) (April 2005 - March 2008)
    Funded by BIRD/Japan Science and Technology Agency (JST) (September 2005 - September 2008)
    Funded by BIRD/Japan Science and Technology Agency (JST) (October 2007 - September 2010)
    Funded by Grant-in-Aid for Publication of Scientific Research Results/Japan Society for the Promotion of Science (JSPS) (April 2011 - March 2012)
    Funded by Grant-in-Aid for Publication of Scientific Research Results/Japan Society for the Promotion of Science (JSPS) (April 2012 - March 2013)
    Supported by the commission for the Development of Artificial Gene Synthesis Technology for Creating Innovative Biomaterial from the Ministry of Economy, Trade and Industry (METI) (October 2012 - March 2016)
    Funded by the project commissioned by the New Energy and Industrial Technology Development Organization (NEDO) (April 2016 -)